Synthesis of functionalized organotrifluoroborates via the 1,3-dipolar cycloaddition of azides
摘要：
[reaction: see text] We have successfully prepared potassium azidoalkyltrifluoroborates from the corresponding halogen compounds in 94-98% yields through a nucleophilic substitution reaction with NaN(3). In the presence of various alkynes and Cu(I) as a catalyst, these azidotrifluoroborates easily formed 1,4-disubstituted organo-[1,2,3]-triazol-1-yl-trifluoroborates in 85-98% yields. This method was then developed into a facile one-pot synthesis for the preparation of various organo-[1,2,3]-triazol-1-yl-trifluoroborates using haloalkyltrifluoroborates as the starting materials.
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关键词：
HIGHLY DIASTEREOSELECTIVE SYN CROSS-COUPLING REACTIONS EFFICIENT AGENTS ANTI CROTYLATION TERMINAL ALKYNES POTASSIUM ALLYLATION CHEMISTRY ALDEHYDES ALKENYL
DOI：
10.1002/chin.200644173
被引量：
年份：
2006
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