Selective C?H Borylation of Alkenes by Palladium Pincer Complex Catalyzed Oxidative Functionalization
摘要:
The CH borylation of simple alkenes catalyzed by palladium pincer complex 1 was performed in the presence of hypervalent iodine and bis(pinacolato)diboron compounds. The borylation reaction probably occurs by a Pd<SUII</SUPd<SUIV</SU oxidationdiboronate transmetalation sequence. TFA=trifluoroacetate.
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DOI:
10.1002/anie.201000690
被引量:
年份:
2010
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