Total synthesis of (+)-macrosphelides A, C, E, F, and G based on enzymatic function
摘要：
The total synthesis of (+)-macrosphelide A ( 1 ) (18.5% overall yield in 11 steps), (+)-macrosphelide C ( 2 ) (25% overall yield in 9 steps), (+)-macrosphelide E ( 3 ) (23.9% overall yield in 11 steps), (+)-macrosphelide F ( 4 ) (20% overall yield in 9 steps), and (+)-macrosphelide G ( 5 ) (22% overall yield in 9 steps) was achieved from a chemoenzymatic reaction product (4 R ,5 S )-4-benzyloxy-5-hydroxy-2( E )-hexenoate 10. Chirality 15:352-359, 2003. 2003 Wiley-Liss, Inc.
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DOI：
10.1002/chir.10203
被引量：
年份：
2010
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