Catalytic Asymmetric Allylation of Aldehydes via a Chiral Indium(III) Complex
摘要:
A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90–96% ee).
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关键词:
HIGHLY STEREOSELECTIVE-SYNTHESIS DOT AG(I) COMPLEX ENANTIOSELECTIVE ALLYLATION HOMOALLYLIC ALCOHOLS EFFICIENT CATALYST AQUEOUS-MEDIA ALDOL REACTION WATER KETONES STANNANES
DOI:
10.1039/b412736f
被引量:
年份:
2005
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