Reactions of carbon dioxide with sodium and lithium borohydrides
摘要：
Sodium borohydride reacts with excess carbon dioxide in the absence of solvent at temperatures somewhat above room temperature to form a fluffy white solid which is thought to be sodium formatomethoxyborate, (NaBO(OCH 3)(O 2CH). When the temperature is lowered, and dimethyl ether is used as a solvent, the reaction product is sodium triformatoborohydride, NaHB(O 2CH) 3. Various other reactions of carbon oxides and sulphides with double hydrides are discussed.
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DOI：
10.1016/0022-1902(58)80250-X
被引量：
年份：
1958
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