Synthesis and characterization of side-chain liquid crystalline polymer containing dichroic dye monomer
摘要:
-toluidino)-4-anthraquinone undecylenate (TAU) (dye-monomer) and 4-allyloxybenzoyl-4-(-propyl-benzoyl)--benzenediol bisate (ABB) (liquid crystalline monomer) side groups were synthesized by copolymeraztion. The molecular structures of the monomers and polymers were confirmed by FT-IR spectroscopy. The optical characterization of the monomer ABB and polymers was made by using polarizing optical microscopy (POM) technique, and their thermal behaviour was investigated by thermogravimetric analyses (TGA) and differential scanning calorimetry (DSC). The conjugate action of the dye (1-(-toluidino)-4-hydroxyl anthraquinone) and the monomer was analyzed by fluorophotometry. Polymers and monomer ABB revealed nematic phase. And DSC results demonstrated that the glass transition temperatures () of the polymers increased with the increase in dye-monomer. TGA result showed that the temperatures at which 5% mass loss occurred () for all the polymers were above 270 °C.
展开
DOI:
10.1016/S0014-3057(03)00067-3
被引量:
年份:
2003
通过文献互助平台发起求助,成功后即可免费获取论文全文。
相似文献
参考文献
引证文献
来源期刊
引用走势
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用!