摘要：

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 24 January 2019 (24.01.2019) WIPO I PCT 01E1°1°1a III m Ho 1111011111° oimIE (10) International Publication Number WO 2019/018103 Al (51) International Patent Classification: B01J 29/70 (2006.01) ClOG 29/12 (2006.01) C07C 2/62 (2006.01) B01J 27/12 (2006.01) C01B 39/02 (2006.01) B01J 23/14 (2006.01) CO7C 2/66 (2006.01) B01J 27/135 (2006.01) (21) International Application Number: PCT/US2018/039396 (22) International Filing Date: 26 June 2018 (26.06.2018) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/534,378 19 July 2017 (19.07.2017) US (71) Applicant: EXXONMOBIL RESEARCH AND EN- GINEERING COMPANY [GB/US]; 1545 Route 22 East, P.O. Box 900, Annandale, NJ 08801-0900 (US). (72) Inventors: NANDI, Partha; 2 Inverrary Place, Annandale, NJ 08801 (US). IDE, Matthew, S.; 1 Woods End Dri- ve, Doylestown, PA 18902 (US). DAKKA, Jihad, M.; 3 Gleim Road, Whitehouse Station, NJ 08889 (US). NIZA- MI, Quddus, A.; 3223 Spring Cypress Road, Apt. 814, Spring, TX 77388 (US). AFEWORKI, Mobae; 24 Kyle Drive, Phillipsburg, NJ 08865 (US). (74) Agent: WRKICH, Joseph, E. et al.; Exxonmobil Research And Engineering Company, 1545 Route 22 East, P.O. Box 900, Annandale, NJ 08801-0900 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: — with international search report (Art. 21(3)) 1-1 O cc O O C (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, (54) Title: ALKYLATION CATALYST (57) : Catalyst compositions with improved alkylation activity and corresponding methods for making such catalyst composi- tions are provided. The catalyst(s) correspond to solid acid catalysts formed by exposing a catalyst precursor with a zeolitic framework structure to a molten metal salt that includes fluorine, such as a molten metal fluoride. The resulting fluorinated solid acid catalysts can have improved alkylation activity while having a reduced or minimized amount of structural change due to the exposure to the molten metal fluoride. This is in contrast to fluorinated solid acid catalysts that are exposed to higher severity forms of fluorination, such as exposure to ammonium fluoride or HF. SnF2 is an example of a suitable molten metal fluoride.

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