ASYMMETRIC DIHYDROXYLATION OF OLEFINS BY OSMIUM TETROXIDE COORDINATED WITHCHIRAL CINCHONA ALKALOID
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30
摘要:
Bisesters of cinchonine, cinchonidine, dihydrocinchonine and dihydrocinchonidine with terephthalic acid and isophthalic acid are used as chiral auxiliaries for osmium tetroxide-catalyzed asymmetric dihydroxylation of olefins such as styrene, a-methylstyrene, methyl cinnamate, ethyl cinnamate, isopropyl cinnamate, cinnamyl alcohol, cyclohexene, 1-methylcyclohexene, 1-phenylcyclohexene, cycloheptene, cyclooctene, 3-chloro-1-propene, 1-hexene and methyl fumarate, and the enantiomeric excess in every case has been determined.
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DOI:
10.1002/(SICI)1099-0690(199809)1998:9<2047::AID-EJOC2047>3.0.CO;
被引量:
年份:
1998
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