Dehydrocyclopentadienyl anion. New aryne

作者:

JC MartinDR Bloch

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摘要:

The syntheses of substituted azomethanes with one, two, and three cyclopropyl substituents on each methyl carbon (1a-e) have been approached via a variety of pathways starting from the appropriate cyclopropylcarbinols. We discuss complicating reactions which arise from the ready ionization of compounds such as tricyclopropylcarbinyl isocyanate and from ring-opening reactions of cyclopropyl...

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DOI:

10.1021/ja00731a024

被引量:

38

年份:

1971

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1996
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