The Catalyst Precursor, Catalyst, and Intermediate in the RuII㏄romoted Asymmetric Hydrogen Transfer between Alcohols and Ketones
摘要：
New insight into the mechanism of catalysis. The purple 16-electron complex 1 and the yellow 18-electron complex 2 directly mediate the asymmetric, Ru(II)-catalyzed hydrogen transfer between secondary alcohols and ketones. Both complexes were characterized by X-ray crystallography.
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DOI：
10.1002/anie.199702851
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年份：
1997
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