Synthesis and absolute stereochemistry of serricornin [(4S,6S,7S)-4,6-dimethyl-7-hydroxy-3-nonanone]. The sex pheromone of the cigarette beetle

阅读量:

51

作者:

K MoriH NomiT ChumanM KohnoK KatoM Noguchi

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摘要:

The absolute stereochemistry o serricornin (4,6-dimethyl-7-hydroxy-3-nonanone) was established as 4 S, 6 S, 7 S by synthesizing both (4 S, 6 S, 7 S)-isomer and its antipode. Only the natural enantiomer was bioactive.

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DOI:

10.1016/0040-4020(82)80081-1

被引量:

376

年份:

1982

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2010
被引量:47

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