Enantioselective Henry reaction catalyzed by a C2-symmetric bis(oxazoline)–Cu(OAc)2·H2O complex
摘要：
AC2-symmetric diethyliPr-bis(oxazoline)–Cu(OAc)2·H2O was found to be an efficient catalyst for catalyzing an enantioselective Henry reaction between nitromethane and various aldehydes to provide β-hydroxy nitroalkanes with high chemical yields (up to 95%) and enantiomeric excesses (up to 97%).
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关键词：
alcohols (benzene compounds nitro compounds (acyclic compounds addition reactions diastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism
DOI：
10.1039/b714153j
被引量：
年份：
2008
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