Toward green catalytic synthesis—Transition metal-catalyzed reactions in non-conventional media
摘要：
Solvents play a critical role in "greening" synthetic chemistry, and this is also true in catalytic organic synthesis. This review attempts to summarize the progress made in the past a few years on homogeneous and heterogeneous catalytic reactions in the non-conventional solvents, water, ionic liquids, supercritical carbon dioxide and fluorous carbons, with the focus on those catalyzed by transition metal complexes. The reactions covered include hydrogenation, hydroformylation, carbonylation, Heck reactions, Suzuki and Stille couplings, Sonogashira reactions, allylic substitution, olefin metathesis, olefin epoxidation and alcohol oxidation.
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关键词：
Catalysis Transition metal complexes Solvent effects Water Ionic liquids Supercritical carbon dioxide Fluorous solvents
DOI：
10.1016/j.molcata.2007.01.003
被引量：
年份：
2007
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