Hydrothermal scavenging of rare-earth elements in the ocean
摘要:
SUSPENDED participate samples collected from the TAG hydrothermal vent field, at 26 ° N on the Mid-Atlantic Ridge, contain 10% of the total rare-earth element content (by volume) of ambient sea water. Shale-normalized distribution patterns show both positive europium anomalies and negative cerium anomalies, indicating that the rare-earth elements in these hydrothermal precipitates come from both hydrothermal vent fluid and seawater sources. Rare-earth/Fe concentration ratios in the suspended p articulate material increase at increasing distances from their hydro-thermal source, indicating that rare-earth elements must be continuously extracted from sea water as hydrothermal precipitates are dispersed through the water column. Therefore, although high-temperature vent fluids escaping from the sea floor are typically enriched 10–10,000 times in rare-earth elements relative to sea water 1–4 , hydrothermal systems must nevertheless act as a net sink in the global ocean budget of the rare-earth elements. But as the maximum rare-earth/Fe ratios observed for suspended particles are 10 times lower than previously reported values for hydrothermal sediments 5–8 , it seems that most of the uptake of rare-earth elements from sea water must occur only after hydrothermal precipitates have settled to the underlying sediments.
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关键词:
Experimental/ geochemistry oceanographic regions oceanography/ midocean ridge chemistry hydrothermal scavenging REE rare earth element North Atlantic seafloor ocean particulate TAG hydrothermal vent fields Mid-Atlantic Ridge precipitates hydrothermal vent fluid Eu Ce/ A9220C Chemistry of the oceans A9330M Atlantic Ocean A9150E Seafloor processes A9150J Marine sedimentation and sediments/ Eu/el Ce/el
DOI:
10.1038/345516a0
被引量:
年份:
1990
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