Hydrothermal scavenging of rare-earth elements in the ocean

来自 EBSCO

阅读量:

323

作者:

CR GermanGP KlinkhammerJM EdmondA MuraH Elderfield

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摘要:

SUSPENDED participate samples collected from the TAG hydrothermal vent field, at 26 ° N on the Mid-Atlantic Ridge, contain 10% of the total rare-earth element content (by volume) of ambient sea water. Shale-normalized distribution patterns show both positive europium anomalies and negative cerium anomalies, indicating that the rare-earth elements in these hydrothermal precipitates come from both hydrothermal vent fluid and seawater sources. Rare-earth/Fe concentration ratios in the suspended p articulate material increase at increasing distances from their hydro-thermal source, indicating that rare-earth elements must be continuously extracted from sea water as hydrothermal precipitates are dispersed through the water column. Therefore, although high-temperature vent fluids escaping from the sea floor are typically enriched 10–10,000 times in rare-earth elements relative to sea water 1–4 , hydrothermal systems must nevertheless act as a net sink in the global ocean budget of the rare-earth elements. But as the maximum rare-earth/Fe ratios observed for suspended particles are 10 times lower than previously reported values for hydrothermal sediments 5–8 , it seems that most of the uptake of rare-earth elements from sea water must occur only after hydrothermal precipitates have settled to the underlying sediments.

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DOI:

10.1038/345516a0

被引量:

539

年份:

1990

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2014
被引量:51

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