Enantioselective alkynylation of a prochiral ketone catalyzed by C2-symmetric diamino diols.

来自 EBSCO

阅读量:

24

作者:

JiangBiaoFengYan

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摘要:

C2-Symmetric diamino diols were used as chiral ligands to induce the asymmetric addition of lithium acetylides to carbonyl groups. The enantiomeric excesses (up to 99% ee) depended on the structure of the acetylene.[Copyright &y& Elsevier]

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年份:

2002

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