Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach

Oxidation reactions are of fundamental importance in nature, and are key transformations in organic synthesis. The development of new processes that employ...

J Piera，Jan‐E. Bckvall - 《Angewandte Chemie》

Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach

Oxidation reactions are of fundamental importance in nature, and are key transformations in organic synthesis. The development of new processes that employ...

J Piera，J Bäckvall - 《Angewandte Chemie International Edition》

Tungsten-catalyzed allylic alkylations. New avenues for selectivity

Oxidation reactions are of fundamental importance in nature, and are key transformations in organic synthesis. The development of new processes that employ...

Barry，M.，Trost，... - 《Journal of the American Chemical Society》

Enantioselective Decarboxylative Alkylation Reactions: Catalyst Development, Substrate Scope, and Mechanistic Studies

-Quaternary ketones are accessed through novel enantioselective alkylations of allyl and propargyl electrophiles by unstabilized prochiral enolate nucleoph...

 - Chemistry - A European Journal

Advancing the Mechanistic Understanding of an Enantioselective Palladium-Catalyzed Alkene Difunctionalization Reaction

The mechanism of an enantioselective palladium-catalyzed alkene difunctionalization reaction has been investigated. Kinetic analysis provides evidence of t...

KH Jensen，JD Webb，MS Sigman - 《Journal of the American Chemical Society》

Structural and kinetic effects of chloride ions in the palladium-catalyzed allylic substitutions

Addition of ligands to [Pd(η 3-allyl)(μ-Cl)] 2 or Cl to [(η 3-allyl)PdL 2] + results in the formation of neutral complexes η 1-allyl-PdClL 2. The reac...

T Cantat，E Génin，C Giroud，... - 《Journal of Organometallic Chemistry》

Palladium-catalyzed oxidations in selective organic synthesis

Palladium-catalyzed oxidations of 1,3-dienes in acetic acid can be controlled to give three main reactions: 1,4-diacetoxylation, 1,4-acetoxychlorination, a...

JE Backvall - 《Pure & Applied Chemistry》

Effect of the Leaving Group on the Rate and Mechanism of the Palladium-Catalyzed Isomerization of Cyclic Allylic Benzoates in Allylic Substitutions

In chloroform, the reaction of cis -5-phenylcyclohex-2-enyl 4-Z-benzoate ( cis - 1 Z, Z = NO2, Cl, H, Me, MeO) with Pd0 complexes ligated to PPh3 is rever...

C Amatore，A Jutand，L Mensah，... - 《European Journal of Organic Chemistry》

Copper-Catalyzed Diacetoxylation of Olefins using PhI(OAc)2as Oxidant

NUB Engineering has chosen the new Hyster Fortens truck for its tough engineering site in Motherwell. Over the last 15 years, Barloworld Handling has devel...

Jayasree，Seayad，Abdul，... - 《Organic Letters》

Palladium-Catalyzed Intramolecular Hydroamination of Allenes Coupled to Aerobic Alcohol Oxidation

Taking the air! A PdII-catalyzed intramolecular hydroamination of allenes coupled to alcohol oxidation has been developed. This reaction is performed by us...

S Qiu，Y Wei，G Liu - Chemistry - A European Journal