Iridium and rhodium complexes bearing a silyl-bipyridine pincer ligand: synthesis, structures and catalytic activity for C–H borylation of arenes
摘要:
Unsaturated 16-electron iridium and rhodium complexes bearing a silyl-bipyridine-based SiNN-pincer ligand (BpySiNN) were synthesised and characterised by X-ray crystallography and NMR spectroscopy. The iridium-BpySiNN complex facilitated the catalytic C(sp2)–H borylation of arenes to give arylboronate esters in high yields (≥93%) under mild conditions (40 °C).
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DOI:
10.1039/D2DT01227H
年份:
2022
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来源期刊
Dalton Transactions
2022/07/05
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