Efficient Synthesis of Diborylalkenes from Alkenes and Diboron by a New PSiP-Pincer Palladium-Catalyzed Dehydrogenative Borylation. Takaya J,Kirai N,Iwasawa ...
Dehydrogenative borylation of alkenes and 1,3-dienes was realized by carrying out the reaction in the presence of bis(pinacolato)diboron (B(2)pin(2)) and a...
Dehydrogenative borylation of alkenes and 1,3-dienes was realized by carrying out the reaction in the presence of bis(pinacolato)diboron (B2pin2) and a cat...
Organic derivatives of boronic acid are widely used reagents useful in various synthetic applications. A fundamental understanding and the exploration of n...
Geminal benzyldiboronates are attractive synthetic building blocks, as two boryl groups and a phenyl group attached to the same carbon, can offer a unique ...
B Lee - Princeton University.;Princeton University.;Princeton University.
The unsymmetrical diborane(4) derivative [(d(CH2P(iPr)2)abB)–Bpin] (1) proved to be a versatile PBP boryl pincer ligand precursor for Co(I) (2a, 4a), Rh(I...
Novel PCP-pincer iridium complexes bearing a diborylmethyl anion were synthesized. Strong 蟽-electron-donation to the metal and significant 蟺-backdonation...
The complextrans-[Rh(Cl)(CO)(PPh3)2] (1) is an efficient catalyst precursor for the dehydrogenative borylation of alkenes without consumption of half the a...
Changing places : Intramolecular B(pin)/H exchange took place in the presence of a platinum-phosphane catalyst, giving synthetically useful cis --methyl-s...
Tridentate PSiP pincer-type palladium complex-catalyzed hydrocarboxylation of allenes under carbon dioxide to give synthetically useful β,γ-unsaturated ...
We present herein a high yield, highly selective catalytic synthesis of vinylboronate esters (VBEs), including 1,1-disubstituted VBEs, from alkenes without...
Diverse kinds of gem- and vic-diborylated compounds are now readily available thanks to advances in gem-diborylation of lithium carbenoids as well as vic-d...
The bis(dihydrogen)ruthenium complex RuH2(H2)2(PCy3)2 (1) catalyzes efficiently the borylation of linear and cyclic alkenes with pinacolborane. Similar res...
