Efficient Synthesis of Diborylalkenes from Alkenes and Diboron by a New PSiP-Pincer Palladium-Catalyzed Dehydrogenative Borylation

J Takaya，N Kirai，N Iwasawa - 《Journal of the American Chemical Society》

Efficient Synthesis of Diborylalkenes from Alkenes and Diboron by a New PSiP-Pincer Palladium-Catalyzed Dehydrogenative Borylation

Department of ChemistryJournal of the American Chemical SocietyTakaya, J.; Kirai, N.; Iwasawa, N. Efficient synthesis of diborylalk- enes from alkenes and diboron by a new PSiP-pincer palla- dium-catalyzed dehydrogenative borylation. ...

J Takaya，N Kirai，N Iwasawa - 《Journal of the American Chemical Society》

PSiP-Pincer Type Palladium-Catalyzed Dehydrogenative Borylation of Alkenes and 1,3-Dienes

Dehydrogenative borylation of alkenes and 1,3-dienes was realized by carrying out the reaction in the presence of bis(pinacolato)diboron (B(2)pin(2)) and a...

N Kirai，S Iguchi，T Ito，... - 《Bulletin of the Chemical Society of Japan》

PSiP-Pincer Type Palladium-Catalyzed Dehydrogenative Borylation of Alkenes and 1,3-Dienes

Dehydrogenative borylation of alkenes and 1,3-dienes was realized by carrying out the reaction in the presence of bis(pinacolato)diboron (B2pin2) and a cat...

N Kirai，S Iguchi，T Ito，... - 《Bulletin of the Chemical Society of Japan》

Oxygenation of a Ruthenium Complex Bearing a PBP-Pincer Ligand Inducing the Formation of a Boronato Ligand with a Weak Ru–O Bond

A ruthenium hydride complex having a boron-containing PBP pincer ligand was synthesized. Oxygenation of this complex by using NMO formed the corresponding ...

T Miyada，M Yamashita - 《Organometallics》

Regioselective Hydroboration of Unsymmetrical Internal Alkynes Catalyzed by a Cobalt Pincer-NHC Complex

Highly regioselective hydroboration of unsymmetrical internal alkynes remains a significant challenge for synthesizing valuable alkenylboronate esters. Her...

NK Meher，M Suryavansi，K Geetharani - 《Organic Letters》

Pitfalls for POCOP-Type Palladium Pincer Complexes in Catalytic Reduction of CO2 with Catecholborane

Reduction of CO2 with catecholborane (HBcat)is knownto be catalyzed by nickel hydride complexes supported by a bis(phosphinite)-basedor POCOP-type pincer l...

A Adhikary，S Saha，NS Kumar，... - 《Organometallics》

Benzyldiboronates: Exploring the Reactivity and Its Application in Ketone Synthesis & Effects of Pincer Rigidification on the Reactivity of Cobalt Complexes

Geminal benzyldiboronates are attractive synthetic building blocks, as two boryl groups and a phenyl group attached to the same carbon, can offer a unique ...

B Lee - Princeton University.;Princeton University.;Princeton University.

Synthesis, Reactivity and Coordination Chemistry of Group 9 PBP Boryl Pincer Complexes: [(PBP)M(PMe3)n] (M = Co, Rh, Ir; n = 1, 2)

The unsymmetrical diborane(4) derivative [(d(CH2P(iPr)2)abB)–Bpin] (1) proved to be a versatile PBP boryl pincer ligand precursor for Co(I) (2a, 4a), Rh(I...

PM Rutz，J Grunenberg，C Kleeberg - 《Molecules》