Role of dimethylformamide in generating the active form of platinum for catalyzing the synthesis of diaryls from aryl iodides
阅读量：
14
摘要：
A mechanism is proposed for the reaction of aryl iodides with platinum(II) tetrachloride complexes in dimethylformamide including formation of PtCl<sub>3</sub>(CONMe<sub>2</sub>)<sup>2−</sup> in the first step through activation of a dimethylformamide C−H bond by platinum(II) and subsequent oxidative addition of ArI to this species.
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DOI：
10.1007/BF02523252
年份：
1998
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