First total synthesis of (−)-diospongin B
摘要:
The first total synthesis of (−)-diospongin B has been achieved starting from benzaldehyde using chiral allylation, a base catalyzed conjugate addition of an α,β-unsaturated ester and an intramolecular oxy-Michael reaction as the key steps in 16% overall yield.
展开
关键词:
Keck allylation Base catalyzed conjugate addition Intramolecular oxy-Michael reaction Diospongin B Substituted tetrahydropyran
DOI:
10.1016/j.tetlet.2005.10.129
被引量:
年份:
2006
通过文献互助平台发起求助,成功后即可免费获取论文全文。
相似文献
参考文献
引证文献
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用!