Transition-Metal-Catalyzed Carbon-Carbon Bond Formation via Carbon-Hydrogen Bond Cleavage

Catalytic functionalization of unreactive C-H bond has become one of the most attractive research subjects in modern organic chemistry. To date, a variety ...

F Kakiuchi，T Kochi - 《Synthesis》

Palladium complexes containing rigid bidentate nitrogen ligands as catalysis for carbon-carbon bond formation

Zerovalent Pd(Ar-BIAN)(dimethyl fumarate) and divalent PdCl 2 (Ar-BIAN) complexes containing the rigid bidentate nitrogen ligand bis(arylimino)acenaphtene ...

RV Asselt，Cornelis J. Elsevier * - 《Tetrahedron》

Carbon-Carbon Bond Formation Using Alkyl-Titanium-(IV) Compounds

with tertiary alkyl halides to form alkanes having quarternary carbon atoms2,3, 2) the above reagents as well as methyltitaniumtriisopropylate react with ...

MT Reetz，RS&B Wenderoth - 《Synthetic Communications》

Copper-catalyzed formation of carbon-heteroatom and carbon—carbon bonds

The present invention relates to copper-catalyzed carbon-heteroatom and carbon-carbon bond-forming methods, such as the reaction of Z-X with C(L)(R)(R′)in the present of a catalyst and a base, thereby forming C(Z)(R)(R′); wherein X rep...

SL Buchwald，A Klapars，JC Antilla，... - US

First-Row d-Block Element-Catalyzed Carbon-Boron Bond Formation and Related Processes

Organoboron reagents represent a unique class of compounds because of their utility in modern synthetic organic chemistry, often affording unprecedented re...

Bose，S Kumar，Lujia，... - 《Chemical Reviews》

First-Row d-Block Element-Catalyzed Carbon-Boron Bond Formation and Related Processes.

Organoboron reagents represent a unique class of compounds because of their utility in modern synthetic organic chemistry, often affording unprecedented re...

S Bose，L Mao，L Kuehn，... - 《Chemical Reviews》

NICKEL-CATALYZED CARBON-CARBON BOND FORMATION REACTIONS

FIRSTLY, ARYL-ALKYL (SP2-SP3) AND ARYL-ALKYL (SP3-SP3) BOND FORMATION REACTIONS BETWEEN ORGANIC HALIDES AND GRIGNARD REAGENTS CATALYZED BY NICKEL COMPLEXES CONTAINING HYBRID N,N,N LIGANDS HAVE BEEN INVESTIGATED. THE APPLICATION OF SIMPLE...

F Xue

Carbon-sulfur bond formation catalyzed by [Pd(IPr~(*OMe)) (cin)Cl] (cin = cinnamyl)

The newly prepared complex [Pd(IPr~(*OMe))(cin)(Cl)] provides high catalytic activity for carbon-sulfur cross-coupling reactions. Nonactivated and deactiva...

GNSP Bastug - 《Journal of Organic Chemistry》

Carbon-carbon bond formation by radical addition-fragmentation reactions of O-alkylated enols.

with organic halides of the type R1R2C(Br)EWG to give the carboxymethylation products R1R2C(EWG)CH2CO2Me, after conversion of the first-formed silyl ...

Yudong，Cai，P Brian，... - 《Organic & Biomolecular Chemistry》