Cross-Coupling Reaction with Lithium Methyltriolborate
摘要:
We newly developed lithium methyltriolborate as an air-stable white solid that is convenient to handle. The good performance of this triolborate for metal-catalyzed bond-forming reactions was demonstrated in palladium-catalyzed cross-coupling reactions with haloarenes. Cross-coupling reaction of [MeB(OCH2)3CCH3]Li with aryl halides occurred in the presence of Pd(OAc)2/RuPhos complex in refluxing MeOH/H2O and the absence of bases.
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DOI:
10.3390/molecules18010430
被引量:
年份:
2012




































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Molecules
2012-12-01
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