Construction of regulated nanospace around a porphyrin core

E. Nemo. "Epoxidation reactions catalyzed by iron porphyrins. Oxygen transfer from Iodosylbenzene". J. Am. Chem. Soc. 1983, 105, 5786-5791. d) K....

M Kimura，T Shiba，M Yamazaki，... - 《Journal of the American Chemical Society》

Hydroxylation and expoxidation reactions catalyzed by synthetic metalloporphyrinates. Models related to the active oxygen species of cytochrome P-450

Iodosylbenzene has been found to react with catalytic amounts of synthetic metalloporphyrinates to give epoxides and alcohols from olefins and alkanes. Tet...

JT Groves，WJ Kruper，TE Nemo，... - 《Journal of Molecular Catalysis》

Hydroxylation and epoxidation catalyzed by iron-porphine complexes. Oxygen transfer from iodosylbenzene

Iodosylbenzene has been found to react with catalytic amounts of synthetic metalloporphyrinates to give epoxides and alcohols from olefins and alkanes. Tet...

John，T.，Groves，... - 《Journal of the American Chemical Society》

On the Mechanism of Epoxidation and Hydroxylation Catalyzed by Iron Porphyrins. Evidence for Non-Intersecting Reaction Pathways

The oxygenation of cyclohexene to cyclohexene oxide and cyclohexen-3-ol by (O)Fe IV TMP + (X) ( 1 ) at various temperatures was compared with the iodosylbenzene mediated reaction catalyzed by chloro-5,10,15,20-tetramesitylporphyrinatoir...

JT Groves，Z Gross - Springer Netherlands

Reaction of Cyclohexene with Iodosylbenzene Catalyzed by Non-Porphyrin Complexesof Iron(III) and Aluminum(III). Newly Discovered Products and a New Mechani...

Iodosylbenzene has been widely used as a source of oxygen atoms in metal-catalyzed oxygenation reactions. Until recently, it has been widely assumed that s...

Y Yang，F Diederich，JS Valentine

Anionic ligand effect on the nature of epoxidizing intermediates in iron porphyrin complex-catalyzed epoxidation reactions

We have studied an anionic ligand effect in iron porphyrin complex-catalyzed competitive epoxidations of cis- and trans-stilbenes by various terminal oxida...

W Nam，SW Jin，MH Lim，... - 《Inorganic Chemistry》

High-yield epoxidations with hydrogen peroxide and tert-butyl hydroperoxide catalyzed by ...

Studies the reactions of hydrogen peroxide or tert-butyl hydroperoxide with cyclooctene and norbornene. Pentafluoroiodosylbenzene as an oxidant which produ...

Taylor，Teddy，G.，... - 《Journal of the American Chemical Society》