Iron-catalyzed intramolecular allylic C-H amination.
摘要：
A highly selective C-H amination reaction under iron catalysis has been developed. This novel system, which employs an inexpensive, nontoxic [Fe(III)Pc] catalyst (typically used as an industrial ink additive), displays a strong preference for allylic C-H amination over aziridination and all other C-H bond types (i.e., allylic > benzylic > ethereal > 3° > 2° 1°). Moreover, in polyolefinic substrates, the site selectivity can be controlled by the electronic and steric character of the allylic C-H bond. Although this reaction is shown to proceed via a stepwise mechanism, the stereoretentive nature of C-H amination for 3° aliphatic C-H bonds suggests a very rapid radical rebound step. 2012 American Chemical Society
展开
DOI：
10.1021/ja211600g
被引量：
年份：
2012
国家科技图书文献中心
(权威机构)
ACS
ACS
(全网免费下载)
掌桥科研
万方医学
查看更多
Semantic Scholar
dx.doi.org
科研支点
科研支点
(全网免费下载)
Europe PMC
NCBI
NCBI
AGRIS
ResearchGate
EBSCO
thieme-connect.com
cheric.org
experts.illinois.edu
chemeurope.com
学术范
onAcademic
bvsalud.org
chemie.de
pubfacts.com
scs.illinois.edu
(全网免费下载)
scs.illinois.edu
(全网免费下载)
mendeley.com
学术范
(全网免费下载)
mysciencework.com
通过文献互助平台发起求助，成功后即可免费获取论文全文。
相似文献
参考文献
引证文献
引用走势
站内活动
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用！
