Gas-phase Inorganic Chemistry: How is it Relevant to Condensed-phase Inorganic Chemistry?

阅读量:

41

作者:

KeithJ.FisherIanG.DanceandGaryD.Willett

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摘要:

Similarities in the methodologies of laser ablation Fourier-transform ion cyclotron resonance mass spectrometry and condensed-phase studies are shown. The reactions of bare gas-phase cations with molecules such as benzenethiol, benzene and sulfur are used to show similarities and differences with condensed-phase systems. The similarity of the gas-phase chemistry of europium Eu<sup>+</sup> with that of the Group II ions Ca<sup>+</sup>, Sr<sup>+</sup> and Ba<sup>+</sup> is highlighted. Copper cyanide anions and cations are used to indicate coordination chemistry in the gas phase. Examples are given to show how the observation of gas-phase ions, particularly the metal-sulfide cluster anions has the potential of guiding condensed-phase syntheses.

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DOI:

10.1002/(SICI)1097-0231(19960115)10:1&lt;106::AID-RCM404&gt;3.0.

年份:

1996

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