Synthesis of 1-methyl-2-diphenylphosphino-3-(1′-isoquinolyl)indole; an easily racemised ligand giving insights into catalytic asymmetric allylation

1-(2-diphenylphosphino-1-naphthyl)isoquinolineResolutionHydroborationIsomerizationThe synthesis of the title compound is described, involving 2-lithiation and ...

TDW Claridge，JM Long，JM Brown，... - 《Tetrahedron》

An Efficient Copper(I)-Catalyst System for the Asymmetric Hydroboration of beta-Substituted Vinylarenes with Pinacolborane

Currently, asymmetric rhodium-catalyzed hydroboration with P,N-chelates, such as quinap (quinap velence 1-(2-diphenylphosphino-1-naphthyl)isoquinoline and ...

Dongwan NohSue Kyoung YoonJiyeon WonJin Yong LeeJaesook Yun - 《Chemistry An Asian Journal》

ChemInform Abstract: A Novel Easily Accessible Chiral Ferrocenyldiphosphine for Highly Enantioselective Hydrogenation. Allylic Alkylation, and Hydroboratio...

The new ligand (R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ((R)-(S)-3a) was prepared in two steps from the commercially available...

A Togni，C Breutel，A Schnyder，... - 《Cheminform》

Asymmetric hydroboration of styrenes catalyzed by cationic chiral phosphine-rhodium(I) complexes

Use of (R)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl (BINAP) as a chiral ligand for the rhodium-catalyzed hydroboration of substituted styrenes (...

MY Lto - 《Tetrahedron Asymmetry》

Resonance Raman Spectroscopy of Soluble Guanylyl Cyclase Reveals Displacement of Distal and Proximal Heme Ligands by NO

The new ligand (R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ((R)-(S)-3a) was prepared in two steps from the commercially available...

AE Yu，S Hu，TG Spiro，... - 《Journal of the American Chemical Society》

Supported highly-polar liquid phase chiral sulfonated binap catalyst for asymmetric synthesis of optically active compounds

The present invention relates to water soluble chiral sulfonated 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl and its use as organometallic catalysts for asymmetric synthesis of optically active compounds. Asymmetric reactions of the pres...

ME Davis，KT Wan - US

Toward New Organometallic Architectures: Synthesis of Carbene-Centered Rhodium and Palladium Bisphosphine Complexes. Stability and Reactivity of [PCBImPRh(L)][PF6] Pincers

The chemical behavior of 1,3-bis(diphenylphosphinomethylene)benzimidazol-2-ylrhodium acetonitrile hexafluorophosphate has been screened under decarbonylation, hydrogenation, and hydroboration reaction conditions. Thus, the PC(BIm)PRh(I) complex ...

A Plikhta，A P?Thig，E Herdtweck，... - 《Inorganic Chemistry》