Molecular magnets Hybrid organic - Inorganic layered compounds with very long-range ferromagnetism
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19
摘要:
The correlations between structures and magnetic properties of new hybrid layered compounds M2(OH)3X (M=Co or Cu), where X is an exchangeable organic anion, are investigated. When the anion is a simple spacer (aliphatic chain), ferromagnetic in-plane interactions dominate, and the situation depends to a large extent on the interlayer spacing d. For small spacings (d<10 ), 3D antiferromagnetic order is stabilized, while large spacings favor spontaneous magnetization, even for d≈40 , due to dipolar through-space interactions. When X is a radical anion, new metal-radical magnets, with d close to 20 , are achieved. Strong interactions between the 3d and π electrons are evidenced, and a net magnetic moment occurs at low temperature. Such compounds are promising for the design of new molecular multiproperty materials.
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DOI:
10.1016/S0010-8545(98)00166-0
被引量:
年份:
1998
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