Synthesis of β-Keto Acids and Methyl Ketones Using Bis(trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides
摘要：
Bis(trimethylsilyl) malonate is acylated in good yields with acid chlorides and acyl carbonates using triethylamine and magnesium or lithium salts to give -keto acids or methyl ketones. Compared to other procedures, which use strong bases, this method is inexpensive, safe and convenient; especially for large scale reactions.
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DOI：
10.1080/00397918508076840
被引量：
年份：
1986
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