Cross-Dehydrogenative Coupling (CDC): Exploring CC Bond Formations beyond Functional Group Transformations

Synthetic chemists aspire both to develop novel chemical reactions and to improve reaction conditions to maximize resource efficiency, energy efficiency, p...

CJ Li - 《Acc Chem Res》

Catalytic C-H functionalization by metal carbenoid and nitrenoid insertion.

Novel reactions that can selectively functionalize carbon-hydrogen bonds are of intense interest to the chemical community because they offer new strategic...

HML Davies，JR Manning - 《Nature》

If C-H bonds could talk: Selective C-H bond oxidation

Review: chemoselectivity of C—H oxidation imposed by the nature of the substrate; ca. 300 refs.

T Newhouse，PS Baran - 《Angewandte Chemie》

A predictably selective aliphatic C-H oxidation reaction for complex molecule synthesis.

Realizing the extraordinary potential of unactivated sp C-H bond oxidation in organic synthesis requires the discovery of catalysts that are both highly re...

MS Chen，MC White - 《Science》

Catalytic carbene insertion into C-H bonds.

A study was conducted to investigate catalytic carbene insertion into C-H bonds. Investigations confirmed that C-C and C-H bond formation with the carbene ...

MP Doyle，R Duffy，M Ratnikov，... - 《Chemical Reviews》

Bu4NI-catalyzed C-O bond formation by using a cross-dehydrogenative coupling (CDC) reaction.

The cr¨me de la cr¨me! A practical and simple Bu4NI-catalyzed CO bond formation was achieved by using a cross-dehydrogenative coupling (CDC) reaction wit...

 - Chemistry - A European Journal

ChemInform Abstract: Facile Synthesis of Vicinal Diamines via Oxidation of N-Phenyltetrahydroisoquinolines with DDQ.

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a Chem...

Althea，S.-K.，Tsang，... - 《Cheminform》

Direct Functionalization of (Un)protected Tetrahydroisoquinoline and Isochroman under Iron and Copper Catalysis: Two Metals, Two Mechanisms

A highly facile, straightforward synthesis of 1-(3-indolyl)-tetrahydroisoquinolines was developed using either simple copper or iron catalysts. N-protected...

M Ghobrial，M Schnürch，MD Mihovilovic - 《Journal of Organic Chemistry》

Organocatalytic enantioselective β-functionalization of aldehydes by oxidation of enamines and their application in cascade reactions

Iminium catalysis, involving the transformation of iminium ions to enamines, has been extensively studied in the context of a number of organic processes. ...

Zhang, Shi-Lei，Xie, He-Xin，J Zhu，... - 《Nature Communications》

Mechanistic investigations of bipyrimidine-promoted palladium-catalyzed allylic acetoxylation of olefins

Several pyridine-like ligands were found to improve Pd(OAc)2-catalyzed allylic oxidation of allylbenzene to cinnamyl acetate by p-benzoquinone in acetic ac...

Bo-Lin Lin, , Jay A Labinger, and , John E Bercaw - 《Revue Canadienne De Chimie》