Synthesis and Structure of the [Ni38Pt6(CO)48H6−n]n− (n=5, 4) Ions: Ni-Pt Clusters as Models for "Cherry" Crystallites
摘要：
A Pt<sub>6</sub> octahedron surrounded by a second octahedron containing 38 Ni atoms forms the metal framework of the cluster ions [Ni<sub>38</sub>Pt<sub>6</sub>(CO)<sub>48</sub>H<sub>6−n</sub>]<sup>n−</sup> (n=3–6), which are easily synthesized from [Ni<sub>6</sub>(CO)<sub>12</sub>]<sup>2−</sup>, PtCl<sub>2</sub>, and H<sup>+</sup>. Such clusters are molecular models for "cherry" crystallites, which are known from catalyst research.
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DOI：
10.1002/anie.198506971
被引量：
年份：
1985
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