␣Kinetic Analysis of Inactivation of the cdc25 Phosphatase by Menadione
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摘要：
ed from C-3 of the monoanionic form of aspartate by an enzyme general base with a pK of 6.3-6.6 in the absence and presence of Mg2+. The resulting carbanion is presum- ably stabilized by delocalization of electrons into the β-car- boxyl with the assistance of a protonated enzyme group in the vicinity of the β-carboxyl. Ammonia is then expelled with
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