Hydroformylation of Alkenes with Rhodium Catalyst in Supercritical Carbon Dioxide
摘要:
1-Octene, 1-decene and styrene have been hydroformylated using a CO 2 -philic fluorous ligand associated with a rhodium catalyst. The effect of P/Rh molar ratio, partial pressure of CO/H 2 and total pressure of carbon dioxide were studied. When 1-octene was used as the substrate, high conversion and selectivity in aldehydes were observed using low rhodium concentration and low P/Rh ratios.
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DOI:
10.1007/s10562-005-0005-7
被引量:
年份:
2006
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