Contrasting styles: The two catalysts shown are both effective for the cyanation of ketimines. The metal-based catalyst 1, developed by a standard approach...
The formation of acrylamide was studied in low-moisture Maillard model systems (180 degrees C, 5 min) based on asparagine, reducing sugars, Maillard interm...
Kinetic, structural, and stereochemical data regarding the mechanism of Ti-catalyzed addition of cyanide to imines in the presence of Schiff base peptide l...
The direct catalytic enantioselective α-amination reaction of carbonyl compounds, a powerful approach to asymmetric carbon–nitrogen bond-forming, has bee...
Examines the mechanism for enantioselective titanium-catalyzed strecker reaction. Consideration of peptide-based metal complexes as bifunctional catalysts...
The mechanisms of decomposition and coloration reaction of L-ascorbic acid are reviewed. At the initial stage of the decomposition, it can be classified roughly into oxidative and non-oxidative processes of decomposition. ASA forms furfu...
in their behavior as heterogeneous catalysts in the three-component, one pot Strecker reaction illustrate the potential of solid solution MOFs to provide the ability to address the various stages involved in the reaction mechanism.doi...
Density functional theory calculations were employed to study the catalytic mechanism, modes of activation, and origin of enantioselectivity of guanidine-c...
In the pursuit of a credible mechanism for the abiotic synthesis of 伪-amino acids, solid-state asymmetric Strecker/retro-Strecker reactions have been demonstrated. Asymmetric addition of cyanide to enantiomorphic crystals of achiral imi...
