Carbon-carbon bond forming reactions of rhenium enolates with terminal alkynes. Evidence for an alkyne C-H oxidative addition mechanism and observation of ...
Carbon-carbon bond forming reactions of rhenium enolates with terminal alkynes. Evidence for an alkyne C-H oxidative addition mechanism and observation of ...
Carbon-carbon bond forming reactions of rhenium enolates with terminal alkynes. Evidence for an alkyne C-H oxidative addition mechanism and observation of ...
Carbon-carbon bond forming reactions of rhenium enolates with terminal alkynes. Evidence for an alkyne C-H oxidative addition mechanism and observation of ...
The ruthenium-catalyzed hydroamidation of terminal alkynes has evolved to become a broadly applicable tool for the synthesis of enamides and enimides. Depe...
The effect of CO 2 on the reaction of a terminal alkyne with CO and H 2O in the presence of PdI 2–KI was studied. With simple 1-alkynes such as alkyl- or ...
The reaction of [Mo2(CO)4(µ-R1C2R2)(η-C5H5)2](R1,R2= H, alkyl, or aryl) with PPh2Cl proceeds via P–Cl bond cleavage and coupling of the diphenylphosph...
The formation mechanism of the active catalyst in the oxidative carbonylation of terminal alkynes at the ≡C-H bond has been investigated for the catalytic...
The mechanism of formation of mer,trans-[(PMe3)(3)Rh(-Cequivalent toC-R)(2)H] from [(PMe3)(4)Rh(Me)] and terminal alkyne has been studied. The initial step of the reaction is the elimination of methane and the formation of the trigonal b...
The mechanism of an iron-catalyzed C—H alkenylation of pivalophenone derivatives with unsymmetric internal alkynes is investigated in details by means of ...
