ChemInform Abstract: Silafunctional Compounds in Organic Synthesis. Part 31. Stereocontrol in Intramolecular Hydrosilation of Allyl and Homoallyl Alcohols: A New Approach to the Stereoselective Synthesis of 1,3〥iol Skeletons
摘要:
Intramolecular hydrosilation of the (racemic) title alkenols is accomplished by procedure A) giving intermediates of type (XV), followed by H2O2/base treatment (procedure B)) to provide the target diols.
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DOI:
10.1002/chin.198705137
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年份:
1987
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2010
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