Hydrophobic acceleration of Diels-Alder reactions
摘要:
The quantitative effect of cosolvents on the water solubility of hydrophobic substrates can be correlated with the effect on reaction rates to determine the geometries of transition states for Diels-Alder reactions, the benzoin condensation, and alkylations of phenoxide ions and aniline. Some of these reactions have transition states with packing of hydrophobic surfaces and some do not....
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DOI:
10.1021/ja00546a048
被引量:
年份:
1980
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