Coherent-incoherent transition and relaxation in condensed-phase tunneling systems

阅读量:

42

作者:

CH MakD Chandler

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摘要:

The tunneling dynamics of the spin-boson problem has been computed using discretized path-integral simulations for temperatures T and couplings, i.e., the Kondo parameter alpha, spanning the entire T-alpha plane. The inherent problem of alternating weights has been solved using a combination of the stationary-phase Monte Carlo method and contour-distortion techniques. A transition from coherent to purely incoherent relaxation was observed for the spin correlation function. The time correlation functions and the location of the coherent-incoherent boundary on the T-alpha plane are well described by the noninteracting-blip approximation. In the deep-tunneling limit of large alpha, low T, and high bath frequency, the system relaxes exponentially, with its relaxation time constant following a power-law temperature dependence, in accord with perturbation theory. At higher T and low bath frequency, the relaxation time crosses over to a classical Arrhenius temperature dependence, reflecting the onset of activated processes. For a narrow region within 1/2 < alpha < 1, numerical results suggest that the system undergoes incoherent relaxation, with a short-time exponential decay, followed by a long-time tail of the power-law type. The short-time exponential relaxation time follows a peculiar power-law temperature dependence, with the relaxation rate increasing as a function of decreasing temperature.

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DOI:

10.1103/PhysRevA.44.2352

被引量:

194

年份:

1991

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1994
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