A convenient synthesis of aziridine-2-carboxylic esters
摘要:
Optically active oxirane-2-carboxylic esters, prepared from allylic alcohols employing the Sharpless epoxidation, were treated with sodium azide. The azido alcohols obtained were subsequently converted into aziridine-2-carboxylic esters by reaction with triphenylphosphine, in good yields and with high optical purity. Various racemic oxirane-2-carboxylic esters were subjected to the same sequence of reactions.
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DOI:
10.1002/recl.19921110101
被引量:
年份:
1992
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