A new efficient synthesis of both enantiomers of macrosphelide core: A potential precursor for functionalized macrosphelides
摘要：
The asymmetric synthesis of a macrosphelide core (1) and its enantiomer was achieved from (S)- or (R)-3-hydroxybutyrate in excellent yields. These compounds are potentially useful precursors for the preparation of biologically important macrosphelide analogues.
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关键词：
pyramidalization alkenes density functional calculations hyperconjugative interactions singlet oxygen
DOI：
10.3987/COM-02-S68
被引量：
年份：
2003
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