Selektive Synthesen mit Organometallen V: Trimethylsilylmethyl‐kalium und andere Spitzenknner unter den Metallierungsmitteln
摘要：
For the metalation of allylic and benzylic positions Me3SiCH2K is the most powerful reagent. BuLi in the presence of KOCMe3, however, can usually replace it. Olefinic and cyclopropane H atoms are most readily attacked by pentylsodium, esp. in the presence of KOCMe3. Me3SiCH2K, however, will work equally if an activating group, such as MeO, is present in the substrate. [on SciFinder (R)]
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关键词：
Genetic algorithms Indexes Power industry Power system restoration Skeleton Switches Genetic algorithm Power system restoration Restructured power industry Skeleton-network reconfiguration
DOI：
10.1002/hlca.19760590212
被引量：
年份：
1976
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