Aqueous Barbier-Grignard type reaction: Scope, mechanism, and synthetic applications

Publication » Aqueous Barbier-Grignard type reaction: Scope, mechanism, and synthetic applications.

CJ Li - 《Tetrahedron》

Interpretation of the unusual behavior of H2O and D2O at low temperatures: Tests of a percolation model

The unusual low‐temperature behavior of liquid water is interpreted using a simple model based upon connectivity concepts from correlated‐site percolatio...

HE Stanley，J Teixeira - 《Journal of Chemical Physics》

Hydrophobic acceleration of Diels-Alder reactions

The quantitative effect of cosolvents on the water solubility of hydrophobic substrates can be correlated with the effect on reaction rates to determine the geometries of transition states for Diels-Alder reactions, the benzoin condensat...

DC Rideout，R Breslow - 《Journal of the American Chemical Society》

Reactivity of Organic Compounds in Hot Water: Geochemical and Technological Implications

Understanding of the reactivity of organic molecules in hot water is developing from studies aimed at explaining how organic matter (kerogen) forms in natu...

SISKIN, M.，KATRITZKY, A. R. - 《Science》

On the origin of product selectivity in aqueous diels-alder reactions

The high endo/exo product ratio in the Diels-Alder reaction of cyclopentadiene with methyl vinyl ketone in water does not reflect aggregation, but the rati...

Ronald，Breslow，and，... - 《Tetrahedron Letters》

1993 R.U. Lemieux Award Lecture Organometallic-type reactions in aqueous media—a new challenge in organic synthesis

The development of organometallic-type reactions in aqueous media is reviewed. Coupling reactions of allyl halides with carbonyl compounds mediated by zinc...

T.H. Chan, , C.J. Li, , M.C. Lee, and , Z.Y. Wei - 《Canadian Journal of Chemistry》

Comparative Diastereoselectivity Analysis of Crotylindium and 3-Bromoallylindium Additions to alpha-Oxy Aldehydes in Aqueous and Nonaqueous Solvent Systems.

ChemInform is a weeklying Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInformof ...

LA Paquette，TM Mitzel - 《Cheminform》

Thermodynamics of unfolding

No Abstract available for this article.

W Kauzmann - 《Nature》

The hydrophobic effect: a reappraisal

What is the reason for the low solubility of non- polar substances in water? Is it true that it is water which expels them? Are the oil drop and the globular state of protein formed by water that avoids contact with non-polar groups or i...

PL Privalov，SJ Gill - 《Pure & Applied Chemistry》

Barbier-Type Allylation of Aldehydes with Active Metallic Antimony

Highly reactive antimony, prepared by the NaBH4 reduction of SbCl3, induced allylation of aldehydes with allylic bromide in DMF/H2O solvent to give good yi...

None - 《Synthetic Communications》