A catalytic enantioselective reaction using a C2-symmetric disulfonamide as a chiral ligand: cyclopropanation of allylic alcohols by the Et2Zn-CH2I2-disulfonamide system
摘要：
The first catalytic, enantioselective Simmons-Smith cyclopropanation of an allylic alochol has been achieved by the reaction of an allylic alcohol with Et2Zn and CH2I2 in the presence of a catalytic amount of chiral disulfonamide 1.
展开
关键词：
cyclopropanation Simmons-Smith reaction chiral Lewis acid enantioselective reaction disulfonamide
DOI：
10.1016/S0040-4039(00)92246-9
被引量：
年份：
1992
相似文献
参考文献
引证文献
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用！
