Synthesis and Characterization of some Transition Metal Complexes of Thiosemicarbazones Derived from 2‐acetylpyrrole and 2‐acetylfuran
摘要:
Copper(II), nickel(II), palladium(II), platinum(II), and silver(I) complexes of 2acetylpyrrole thiosemicarbazone (H2L1) and copper(II), nickel(II), platinum(II) and zinc(II) complexes of 2acetylfuran thiosemicarbazone (HL2) have been prepared and characterized by conductance, electronic, infrared, magnetic and 1H NMR spectral measurements in addition to elemental and thermogravimetrical analyses. Squareplanar structures are suggested for the H2L1 complexes of Cu(II), Ni(II), Pd(II) and Pt(II), whereas octahedral structures proposed for the HL2 complexes of Cu(II) and Ni(II); the Zn(II) and Ag(I) complexes are tetrahedral. Moreover, the results showed that the ligand H2L1 is bidentate in all of its complexes, and the ligand HL2 is either mono, di or tridentate.
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DOI:
10.1081/SIM-200059215
被引量:
年份:
2005
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