Mechanistic Insights into Cu‐Catalyzed Asymmetric Aldol Reactions: Chemical and Spectroscopic Evidence for a Metalloenolate Intermediate
摘要：
In situ IR spectroscopy and transmetalation experiments confirm a postulated catalytic cycle. The metalloenolate 1 describes the active intermediate in the aldol reaction catalyzed by [CuF2{(S)-tol-binap}] (see reaction scheme). (S)-tol-binap=(S)-(-)-2,2-bis(di-p-tolylphosphanyl)-1,1-binaphthyl.
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DOI：
10.1002/(SICI)1521-3773(19981204)37:22<3124::AID-ANIE3124>3.0.CO
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年份：
2010
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