Introduction to Cross-Coupling Reactions

The cross-coupling reaction of organometallic reagents with organic electrophiles in the presence of group 8– 10 metal catalysts, notably nickel and palla...

T Kohei，N Miyaura - Springer Berlin Heidelberg

Introduction to Cross-Coupling Reactions

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K Tamao，N Miyaura - 《Cheminform》

Organotrifluoroborates: Protected Boronic Acids that Expand the Versatility of the Suzuki Coupling Reaction

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a Chem...

GA Molander，N Ellis - 《Cheminform》

Catalytic Cycle of Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids. Arylrhodium, Oxa-π-allylrhodium, and Hydroxorhodium Intermediates

The catalytic cycle of asymmetric 1,4-addition of phenylboronic acid to an α,β-unsaturated ketone catalyzed by a rhodium−binap complex was established by use of RhPh(PPh3)(binap) as a key intermediate. The reaction proceeds through ...

Tamio，Hayashi，Makoto，... - 《Journal of the American Chemical Society》

Copper-catalyzed general CN and CO bond cross-coupling with arylboronic acid

General catalytic Cu(OAc) 2/TEMPO in air or Cu(OAc) 2/O 2 systems for the CN and CO cross-coupling reactions with arylboronic acid have been discovered...

PYS Lam，G Vincent，CG Clark，... - 《Tetrahedron Letters》

Ir-Catalyzed Borylation of CH Bonds in N-Containing Heterocycles: Regioselectivity in the Synthesis of Heteroaryl Boronate Esters

(Chemical Equation Presented) Blocking the way: Substitution at the 2-position in pyridines and other N-heterocycles blocks N-coordination to an Ir center....

IAI Mkhalid，DN Coventry，D Albesa-Jove，... - 《Angewandte Chemie》

Ir-catalyzed borylation of C-H bonds in N

Mkhalid IA, Coventry DN, Albesa-Jove D, Batsanov AS, Howard JA, Perutz RN, Marder TB.

Ibraheem A. I. Mkhalid，David N. Coventry，D Albesa-Jove，... - 《Angewandte Chemie International Edition》

Complete Regioselection in Palladium-Catalyzed Arylation and Alkenylation of Allylic Alcohols with Hypervalent Iodonium Salts.

Total synthesis of the extraordinary antineoplastic constituent, dolastatin 10, from the Indian Ocean mollusc Dolabella auricularia has been summarized. Th...

SK Kang，HW Lee，SB Jang，... - 《Journal of Organic Chemistry》

Palladium-catalyzed arylation of polar organometallics mediated by 9-methoxy-9-borabicyclo[3.3.1]nonane: Suzuki reactions of extended scope

An alternative way for performing Suzuki reactions is presented. The necessary borate which is the actual nucleophile in these palladium catalyzed C-C-bond formations is prepared from 9-methoxy-9-bora-bicyclo[3.3.1]nonane (9-OMe-9-BBN) a...

Alois，Fürstner，and，... - 《Tetrahedron》

Crystal and molecular structure of hexadecamethylcyclooctasiloxane, [(CH 3 ) 2 SiO] 8

Crystals of hexadecamethylcyclooctasiloxane are tetragonal, =13.9442(5), =8.5573(4), =2, space group 4/. The structure was solved by direct methods and was...

Norman L. Paddock, , Steven J. Rettig, and , James Trotter - 《Canadian Journal of Chemistry》