Di-tert-butyl Peroxide-Promoted α-Alkylation of α-Amino Carbonyl Compounds by Simple Alkanes
摘要：
A di-tert butyl peroxide (DTBP)-promoted α-alkylation of α-amino carbonyl compounds by simple alkanes is developed, proceeding through dual sp(3) C-H bonds cleavage. The reaction was applicable for α-amino ketones and α-amino esters, providing a facile pathway for the α-functionalization of these substrates. The radical pathway is involved in this transformation.
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关键词：
C‐C bond formation amines (benzene compounds ketones (acyclic compounds ketones (benzene compounds
DOI：
10.1021/jo5017426
被引量：
年份：
2014
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