Asymmetric synthesis of N,O,O,O-tetra-acetyl D-lyxo-phytosphingosine, jaspine B (pachastrissamine) and its C(2)-epimer
摘要：
The highly diastereoselective conjugate addition of lithium ( S)- N-benzyl- N-(α-methylbenzyl)amide to a γ-silyloxy-α,β-unsaturated ester and in situ enolate oxidation with (+)-(camphorsulfonyl)oxaziridine has been used as the key step in the asymmetric synthesis of N, O, O, O-tetra-acetyl d- lyxo-phytosphingosine, jaspine B (pachastrissamine) and its C(2)-epimer.
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DOI：
10.1016/j.tetasy.2007.10.026
被引量：
年份：
2007
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