ChemInform Abstract: Catalytic Asymmetric Aldol Reaction: Reaction of Aldehydes with Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex.
摘要：
Aldol reaction of ,-dialkyl-α-isocyanoacetamides with primary alkyl aldehydes in the presence of 0.5–1 mol% of a chiral (aminoalkyl) ferrocenylphosphine-gold(I) catalyst proceeded with high enantio- and diastereoselectivity to give trans-5-alkyl-2-oxazoline-4-carboxamides of up to 98.6% ee, which were converted into optically active threo-β-hydroxyamino acids.
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DOI：
10.1002/chin.198706172
被引量：
年份：
1987
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